Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

Cohalogenation of Allyl and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH− -form) vinyl silanes are converted into epoxysilanes.

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Bibliographische Detailangaben
Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2001-01, Vol.6 (1), p.61-66
Hauptverfasser: Domann, Silvie, Sourkouni-Argirusi, Georgia, Merayo, Nuria, Schönberger, Andreas, Kirschning, Andreas
Format: Artikel
Sprache:eng
Schlagworte:
allylsilane
Automation
Cohalogenation
polymer-supported reagent
Polymers
Reagents
vinylsilane
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Beschreibung
Zusammenfassung:Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OH− -form) vinyl silanes are converted into epoxysilanes.
ISSN:1420-3049
1420-3049
DOI:10.3390/60100061