Preparation, characterization, and antibacterial effect of bio-based modified starch films

•Preparation of bio-based modified starch film.•Performance characterization of bio-based modified starch film.•The composite membrane has bacteriostatic effect and good cytocompatibility. There are several problems with common starch films, including strong water absorption and poor mechanical properties. To create a better starch film, octenyl succinate cassava starch ester (OSCS) was first blended with chitosan and nano ZnO to prepare an OSCS/CS/ZnO film. Then, the film was supplemented with different concentrations of ε-PL as a bacteriostatic agent to prepare a film that would resist bacterial invasion. The mechanical properties, barrier properties, optical properties, and color of the modified starch antibacterial films were investigated, and finally the antibacterial properties and cytotoxicity were tested. The results demonstrated that the modified starch antibacterial film had good mechanical properties, improved surface hydrophobicity, and had a UV-blocking effect. The modified starch antibacterial film with ε-PL of 8% had stable and long-lasting antibacterial properties, stable release, and good cytocompatibility. An active packaging material was successfully prepared using ε-PL and had a strong preservative effect on food.