Type‐II Dirac Nodal Lines in a Double‐Kagome‐Layered Semimetal

Lorentz‐violating type‐II Dirac nodal line semimetals (DNLSs), hosting curves of band degeneracy formed by two dispersion branches with the same sign of slope, represent a novel state of matter. While being studied extensively in theory, convincing experimental evidence of type‐II DNLSs remain elusive. Recently, vanadium‐based kagome materials have emerged as a fertile ground to study the interplay between lattice symmetry and band topology. This work studies the low‐energy band structure of double‐kagome‐layered CsV8Sb12 and identifies it as a scarce type‐II DNLS protected by mirror symmetry. This work observes multiple DNLs consisting of type‐II Dirac cones close to or almost at the Fermi level via angle‐resolved photoemission spectroscopy (ARPES), which provides an electronic explanation for the nonsaturating magnetoresistance effect as observed. First‐principles theory analyses show that spin‐orbit coupling only opens a small gap, resulting in effectively gapless ARPES spectra, yet generating large spin Berry curvature. These type‐II DNLs, together with the interaction between a low‐energy van Hove singularity and quasi‐one‐dimensional band as observed in the same material, suggest CsV8Sb12 as an ideal platform for exploring novel transport properties. Recently, vanadium‐based kagome materials have emerged as a fertile ground to study the interplay between exotic orders. Combining angle‐resolved photoemission spectroscopy and density‐functional theory, double‐kagome‐layered CsV8Sb12 is identified as a scarce type‐II Dirac nodal line semimetal, together with the interaction between van Hove singularity and quasi‐one‐dimensional band, suggesting CsV8Sb12 as an ideal platform for exploring novel transport properties.