Direct Synthesis of ESBO Derivatives-18O Labelled with Dioxirane

Direct Synthesis of ESBO Derivatives-18O Labelled with Dioxirane

This work addresses a new approach developed in our laboratory, consisting in the application of isolated dimethyldioxirane (DDO, 1a) labelled with 18O for synthesis of epoxidized glyceryl linoleate (Gly-LLL, 2). We expect that this work could contribute in improving analytical methods for the deter...

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Veröffentlicht in:TheScientificWorld 2013, Vol.2013 (2013), p.1-7
Hauptverfasser: Fusco, Caterina, Tommasi, Immacolata, Suman, Michele, Annese, Cosimo, La Tegola, Stefano, D'Accolti, Lucia
Format: Artikel
Sprache:eng
Schlagworte:
Dimethyldioxirane
Dioxirane
Epoxy Compounds - chemistry
Food
Mass spectrometry
Molecular Structure
Oils & fats
Organic chemistry
Oxygen Isotopes - chemistry
Potassium
Scientific imaging
Soybean oil
Soybean Oil - chemistry
Soybeans
Synthesis
Triglycerides
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Beschreibung
Zusammenfassung:This work addresses a new approach developed in our laboratory, consisting in the application of isolated dimethyldioxirane (DDO, 1a) labelled with 18O for synthesis of epoxidized glyceryl linoleate (Gly-LLL, 2). We expect that this work could contribute in improving analytical methods for the determination of epoxidized soybean oil (ESBO) in complex food matrices by adopting an 18O-labelled-epoxidized triacylglycerol as an internal standard.
ISSN:2356-6140
1537-744X
DOI:10.1155/2013/212156