Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol

In the title compound, C 15 H 11 F 3 N 2 O 4 , the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intramolecular bifurcated O—H...(N,O) hydrogen bond with S (6) and S (9) ring motifs. In the crystal, molecules are l...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-07, Vol.71 (7), p.o466-o467
Hauptverfasser: Karadayı, Nevzat, Şahin, Songül, Köysal, Yavuz, Coşkun, Emine, Büyükgüngör, Orhan
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Sprache:eng
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Zusammenfassung:In the title compound, C 15 H 11 F 3 N 2 O 4 , the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intramolecular bifurcated O—H...(N,O) hydrogen bond with S (6) and S (9) ring motifs. In the crystal, molecules are linked by C—H...O hydrogen bonds into a helical chain along the 3 1 screw axis parallel to c . The –CF 3 group shows rotational disorder over two sites, with occupancies of 0.39 (2) and 0.61 (2).
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989015010129