Crystal structure of 2-{[2-methoxy-5-(trifluoromethyl)phenyl]iminomethyl}-4-nitrophenol
In the title compound, C 15 H 11 F 3 N 2 O 4 , the N=C bond of the central imine group adopts an E conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intramolecular bifurcated O—H...(N,O) hydrogen bond with S (6) and S (9) ring motifs. In the crystal, molecules are l...
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Veröffentlicht in: | Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-07, Vol.71 (7), p.o466-o467 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, C
15
H
11
F
3
N
2
O
4
, the N=C bond of the central imine group adopts an
E
conformation. The dihedral angle between two benzene rings is 6.2 (2)°. There is an intramolecular bifurcated O—H...(N,O) hydrogen bond with
S
(6) and
S
(9) ring motifs. In the crystal, molecules are linked by C—H...O hydrogen bonds into a helical chain along the 3
1
screw axis parallel to
c
. The –CF
3
group shows rotational disorder over two sites, with occupancies of 0.39 (2) and 0.61 (2). |
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ISSN: | 2056-9890 2056-9890 |
DOI: | 10.1107/S2056989015010129 |