Direct Z-Scheme Heterojunction Catalysts Constructed by Graphitic-C3N4 and Photosensitive Metal-Organic Cages for Efficient Photocatalytic Hydrogen Evolution

The demand for improving the activity, durability, and recyclability of metal-organic cages (MOCs) that work as photocatalytic molecular devices in a homogeneous system has promoted research to combine them with other solid materials. An M2L4 type photosensitive metal-organic cage MOC-Q2 with light-...

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Veröffentlicht in:Nanomaterials (Basel, Switzerland) Switzerland), 2022-03, Vol.12 (5), p.890
Hauptverfasser: Lv, Chuying, Qin, Su, Lei, Yang, Li, Xinao, Huang, Jianfeng, Liu, Junmin
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Sprache:eng
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Zusammenfassung:The demand for improving the activity, durability, and recyclability of metal-organic cages (MOCs) that work as photocatalytic molecular devices in a homogeneous system has promoted research to combine them with other solid materials. An M2L4 type photosensitive metal-organic cage MOC-Q2 with light-harvesting ligands and catalytic Pd2+ centers has been synthesized and further heterogenized with graphitic carbon nitride to prepare a robust direct Z-scheme heterojunction photocatalyst for visible-light-driven hydrogen generation. The optimized g-C3N4/MOC-Q2 (0.7 wt%) sample exhibits a high H2 evolution activity of 6423 μmol g−1 h−1 in 5 h, and a total turnover number of 39,695 after 10 h, significantly superior to the bare MOC-Q2 used in the homogeneous solution and the comparison sample Pd/g-C3N4/L-4. The enhanced performances of g-C3N4/MOC-Q2 can be ascribed to its direct Z-scheme heterostructure, which effectively improves the charge separation and transfer efficiency. This work presents a rational approach of designing a binary photocatalytic system through combing micromolecular MOCs with heterogeneous semiconductors for water splitting.
ISSN:2079-4991
2079-4991
DOI:10.3390/nano12050890