N -Ferrocenylmethyl-2-nitroaniline

N -Ferrocenylmethyl-2-nitroaniline

In the title compound, [Fe(C5H5)(C12H11N2O2)], the two cyclopentadienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitrobenzenamine group, which is essentially per...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-10, Vol.68 (10), p.m1318-m1318
Hauptverfasser: Rahim, Oumelkheir, Khelef, Abdelhamid, Terki, Belgacem, Mahboub, Mohammed Sadok, Lanez, Touhami
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [Fe(C5H5)(C12H11N2O2)], the two cyclopentadienyl (Cp) rings are nearly eclipsed and parallel to each other, the dihedral angle between their mean planes being 2.54 (1)°. One of the Cp rings is substituted by a nitrobenzenamine group, which is essentially perpendicular to the substituted cyclopentadienyl ring, with an N—C(H2)—C—C torsion angle of 89.8 (2)°. Intramolecular N—H...O and N—H...N hydrogen bonds occur. In the crystal, weak C—H...O hydrogen bonds link adjacent molecules.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812039177