Crystal structure of bis(β-alaninium) tetrabromidoplumbate

Crystal structure of bis(β-alaninium) tetrabromidoplumbate

The title compound, poly[bis(β-alaninium) [[dibromidoplumbate]-di-μ-dibromido]] {(C 2 H 8 NO 2 ) 2 [PbBr 4 ]} n or ( β -AlaH) 2 PbBr 4 , crystallizes in the monoclinic space group P 2 1 / n . The (PbBr 4 ) 2− anion is located on a general position and has a two-dimensional polymeric structure. The P...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2024-09, Vol.80 (9), p.931-935
Hauptverfasser: Tonoyan, Gayane S., Giester, Gerald, Ghazaryan, Vahram V., Chilingaryan, Ruben Yu, Margaryan, Arthur A., Mkrtchyan, Artak H., Petrosyan, Aram M.
Format: Artikel
Sprache:eng
Schlagworte:
bromoplumbate
crystal structure
hybrid crystal
organic–inorganic crystal
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Zusammenfassung:The title compound, poly[bis(β-alaninium) [[dibromidoplumbate]-di-μ-dibromido]] {(C 2 H 8 NO 2 ) 2 [PbBr 4 ]} n or ( β -AlaH) 2 PbBr 4 , crystallizes in the monoclinic space group P 2 1 / n . The (PbBr 4 ) 2− anion is located on a general position and has a two-dimensional polymeric structure. The Pb center is holodirected. The supramolecular network is mainly based on O—H...Br, N—H...Br and N—H...O hydrogen bonds.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989024007722