Crystal Structure of ( E )-2-(3,3,3-tri-fluoro-prop-1-en-1-yl)aniline

The mol-ecule of the title compound, C H F N, adopts an configuration with respect to the C=C double bond. The dihedral angle between the benzene ring and the prop-1-enyl group is 25.4 (3)°. In the crystal, mol-ecules are linked pairs of N-H⋯F hydrogen bonds into inversion dimers with an (16) ring m...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2018-10, Vol.74 (Pt 10), p.1448-1450
Hauptverfasser: Kubono, Koji, Tani, Keita, Omote, Masaaki, Ogawa, Futa, Matsumoto, Taisuke
Format: Artikel
Sprache:eng
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Zusammenfassung:The mol-ecule of the title compound, C H F N, adopts an configuration with respect to the C=C double bond. The dihedral angle between the benzene ring and the prop-1-enyl group is 25.4 (3)°. In the crystal, mol-ecules are linked pairs of N-H⋯F hydrogen bonds into inversion dimers with an (16) ring motif. The dimers are linked by C-H⋯N hydrogen bonds, forming a ribbon structure along the axis direction. The ribbons are linked by N-H⋯π and C-H⋯π inter-actions, generating a three-dimensional network.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989018012756