Synthesis and structure of сopper(II) thiocyanate and nitrate complexes with 1-tert-butyl1H-1,2,4-triazolе

Complexes [Сu(NCS)2L3], [Сu(NO3)2L4] and [Cu(NCS)2L4]·L have been prepared by direct synthesis involving the interaction of metallic copper, ammonium salts NH4X (Х = NCS, NO3) and 1-tert-butyl-1H-1,2,4-triazole (L). Their composition and structure were determined by elemental analysis, single crysta...

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Veröffentlicht in:Zhurnal Belorusskogo gosudarstvennogo universiteta. Khimii͡a 2022-04 (1), p.83-95
Hauptverfasser: Degtyarik, Mikhail M., Lyakhov, Alexander S., Grigorieva, Inna M., Ivashkevich, Ludmila S., Grigoriev, Yuri V., Ivashkevich, Oleg A.
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Sprache:bel ; eng
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Zusammenfassung:Complexes [Сu(NCS)2L3], [Сu(NO3)2L4] and [Cu(NCS)2L4]·L have been prepared by direct synthesis involving the interaction of metallic copper, ammonium salts NH4X (Х = NCS, NO3) and 1-tert-butyl-1H-1,2,4-triazole (L). Their composition and structure were determined by elemental analysis, single crystal X-ray analysis, and IR spectroscopy (range of 4000–500 cm–1). All the complexes showed mononuclear structure. In them triazole acts as a monodentate ligand, being coordinated by the N4 atom of the heterocycle. The NCS– and NO–3 anions display monodentate N- and O-coordination, accordingly. In [Сu(NCS)2L3], copper(II) cation has square-pyramidal environment of nitrogen atoms of two ligands L and two thiocyanate anions in the basal sites, and one nitrogen atom of ligand L in the apical position. In complexes [Сu(NO3)2L4] and [Cu(NCS)2L4]·L, copper(II) cations are octahedrally surrounded by nitrogen atoms of ligand L in the equatorial sites and by O or N atoms of corresponding anions in the axial positions.
ISSN:2520-257X
2617-3980
DOI:10.33581/2520-257X-2022-1-83-95