Tris[dimethyl (benzoylamido)phosphato-κ 2 O , O ′](1,10-phenanthroline-κ 2 N , N ′)neodymium(III)

Tris[dimethyl (benzoylamido)phosphato-κ 2 O , O ′](1,10-phenanthroline-κ 2 N , N ′)neodymium(III)

In both independent mol­ecules of the title compound, [Nd(C 9 H 11 NO 4 P) 3 (C 12 H 8 N 2 )], the Nd III atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodeca­hedral geometry. In the phosphoryl ligands, the benzene rings are twis...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-03, Vol.69 (3), p.m143-m143
Hauptverfasser: Kariaka, Nataliia S., Trush, Victor A., Medviediev, Volodymyr V., Sliva, Tetyana Yu, Amirkhanov, Vladimir M.
Format: Artikel
Sprache:eng
Schlagworte:
Metal-Organic Papers
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In both independent mol­ecules of the title compound, [Nd(C 9 H 11 NO 4 P) 3 (C 12 H 8 N 2 )], the Nd III atom is coordinated by six O atoms belonging to three phosphoryl ligands and two N atoms of 1,10-phenanthroline in a dodeca­hedral geometry. In the phosphoryl ligands, the benzene rings are twisted with respect to the planes of the sp 2 -hybridized C atoms of the chelate rings by 12.1 (1)–24.7 (1)°.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813003462