A comparative study on the microstructure and performance stability of Cu-Al2O3 and Cu-Y2O3 alloys after high-temperature annealing

•Cu-Y2O3 exhibits faster mechanical properties degradation at annealing at ≥800 °C.•The grain growth activation energy of Cu-Y2O3 is lower than Cu-Al2O3.•The activation energy of Y2O3 nanoparticles coarsening is higher than Al2O3 nanoparticles.•Rapid grain growth is the main reason for degradation o...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Nuclear materials and energy 2023-09, Vol.36, p.101480, Article 101480
Hauptverfasser: Sun, Xiaoyuan, Zhang, Yifan, Ma, Bing, Wang, Jing, Luo, Laima, Wu, Yucheng
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•Cu-Y2O3 exhibits faster mechanical properties degradation at annealing at ≥800 °C.•The grain growth activation energy of Cu-Y2O3 is lower than Cu-Al2O3.•The activation energy of Y2O3 nanoparticles coarsening is higher than Al2O3 nanoparticles.•Rapid grain growth is the main reason for degradation of Cu-Y2O3. This study presents a comparative analysis of the microstructure and performance stability of Cu-Al2O3 and Cu-Y2O3 alloy after annealing at temperatures ranging from 600 °C to 1000 °C. The evolution of grain size, nanoparticle size, and mechanical properties was investigated using transmission electron microscopy (TEM), scanning electron microscope (SEM), electron backscattered diffraction (EBSD), X-ray diffraction (XRD) and mechanical tests. The results indicate a more rapid degradation of yield strength and ultimate tensile strength in Cu-Y2O3 alloy after annealing at a temperature of ≥800 °C, while the mechanical properties of Cu-Al2O3 are relatively stable. The main cause of the decrease in mechanical properties is attributed to the rapid grain growth observed under annealing temperatures of ≥800 °C. Cu-Y2O3 alloy exhibited lower grain size stability, and the activation energy of grain growth was estimated to be 115 kJ/mol, which is lower than that of Cu-Al2O3 but comparable to the value reported in the literature for CuCrZr alloy. In contrast, the activation energies for coarsening of Y2O3 and Al2O3 nanoparticles were determined to be 58.9 kJ/mol and 44.1 kJ/mol, respectively. These results indicate that Y2O3 nanoparticles were found to be more stable than Al2O3 nanoparticles.
ISSN:2352-1791
2352-1791
DOI:10.1016/j.nme.2023.101480