Diacetato-(N,N-diethyl-ethylenediamine)-zinc(II)

In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl-ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra-hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with tw...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-08, Vol.66 (Pt 8), p.m940-m940
Hauptverfasser: Kim, Young-Inn, Yun, Sun-Young, Lee, Taewoo, Kang, Sung Kwon
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Sprache:eng
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Zusammenfassung:In the title compound, [Zn(CH(3)COO)(2)(C(6)H(16)N(2))], the Zn(II) atom is coordinated by two N atoms of one bidentate diethyl-ethylenediamine ligand and two O atoms of two acetate anions in a distorted tetra-hedral geometry. The acetate ligands are asymmetrically coordinated to the Zn atom with two different C-O distances of 1.234 (4) and 1.275 (4) Å. The dihedral angle between the N/Zn/N and O/Zn/O planes is 83.11 (8)°. There are two independent mol-ecules in the asymmetric unit. N-H⋯O hydrogen bonding links mol-ecules into a three-dimensional network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810027418