1-[(E)-4-(Phenyl-diazen-yl)phen-yl]-3-pyrroline-2,5-dione

The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The mol-ecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-09, Vol.67 (Pt 9), p.o2333-o2333
Hauptverfasser: Rusu, Elena, Shova, Sergiu, Rusu, Gheorghe
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Sprache:eng
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Zusammenfassung:The title compound, C(16)H(11)N(3)O(2), displays a trans configuration with respect to the azo group. The mol-ecule is non-planar; the maleimide ring forms a dihedral angle of 42.35 (4)° with the benzene ring bonded to its N atom and the mean plane of this benzene ring is rotated by 21.46 (8)° with respect to the azo group mean plane, which, in turn, forms a dihedral angle of 24.48 (7)° with the 'terminal' benzene ring. Mol-ecules in the crystal are π-π stacked along the [100] direction with a mean inter-planar distance of 3.857 (1) Å. In addition, C-H⋯O inter-actions link them into double layers parallel to the ac plane.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053681103193X