Metal Mobilization From CO2 Storage Cap-Rocks: Experimental Reactions With Pure CO2 or CO2 SO2 NO

CO 2 geological storage will be needed as part of the transition to lower greenhouse gas emissions. During CO 2 storage, the mobilization of metals from minerals to formation water via CO 2 water rock reactions may be a concern for water quality. The sources, behavior, and fate of metals, however, are not well understood. Metals in minerals of calcite cemented sandstone, feldspar-rich sandstone, and ironstone seal drill cores from a target storage site were characterized. The cores were reacted with low-salinity water and pure supercritical CO 2 or impure CO 2 with SO 2 and nitric oxide (NO), under reservoir conditions. Calcite cemented core underwent calcite dissolution with chlorite, plagioclase, and sulfide alteration. The highest concentrations of calcium and manganese were released in the reaction of calcite cemented sandstone seal, with the lowest mobilized arsenic concentration. Pure CO 2 reaction of the feldspar-rich sandstone seal resulted in calcite dissolution, with plagioclase, chlorite, kaolinite, illite, and sulfides corroded. Impure CO 2 reaction of the feldspar-rich sandstone led to additional corrosion of apatite, pyrite, and sphalerite cements. Generally, dissolved iron, lead, zinc, and arsenic were released and then re-precipitated in oxide minerals or adsorbed. Calcium, manganese, and strontium were released primarily from calcite cement dissolution. Plagioclase corrosion was a second source of dissolved strontium, and chlorite dissolution a second source of manganese. Although sulfides contained higher concentrations of metals, the higher reactivity of carbonates meant that the latter were the main sources contributing to dissolved metal concentrations. The mineral content of the seal cores, and the injected gas mixture, had an impact on the type and concentration of metals released. The ubiquitous presence of carbonate minerals means that this study is applicable to understanding the potential risk factors for water quality changes, and the mobilization and fate of environmentally regulated metals, in both CO 2 storage complexes and overlying drinking water aquifers worldwide.