Chiral Phosphoric Acid Diesters as Ligands in Asymmetric Transition Metal Catalyzed Hydrogenation

Chiral Phosphoric Acid Diesters as Ligands in Asymmetric Transition Metal Catalyzed Hydrogenation

A chiral phosphoric acid diester, specifically the BINOL-based derivative, has been used for the first time in Rh-, Ir-, and Pd-catalyzed hydrogenation of olefins and imines, giving ee-values of up to 85%.

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Veröffentlicht in:Chimia 2003-05, Vol.57 (5), p.290
Hauptverfasser: Reetz, Manfred T., Sell, Thorsten, Goddard, Richard
Format: Artikel
Sprache:eng
Schlagworte:
Asymmetric catalysis
Chirality
Hydrogenation
Iridium
Palladium
Phosphorus ligands
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Zusammenfassung:A chiral phosphoric acid diester, specifically the BINOL-based derivative, has been used for the first time in Rh-, Ir-, and Pd-catalyzed hydrogenation of olefins and imines, giving ee-values of up to 85%.
ISSN:0009-4293
2673-2424
DOI:10.2533/000942903777679316