Hexaethylguanidinium Salts

Hexaethylguanidinium Salts

Crystal structures of five hexaethylguanidinium salts (PF6- 1, FeCl4- 2, CuCl42-*H2O 3, CoBr42-/Br-*H2O 4, bistriflimide 5) were determined. Short interionic contacts were identified. Cyclic voltammetry of 2 revealed an electrochemical window from +1.0 to -1.5 V with a single Fe(III)/Fe(II) redox ev...

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Veröffentlicht in:Crystals (Basel) 2014-09, Vol.4 (3), p.404-416
Hauptverfasser: Salchner, Robert, Kahlenberg, Volker, Gelbrich, Thomas, Wurst, Klaus, Rauch, Martin, Laus, Gerhard, Schottenberger, Herwig
Format: Artikel
Sprache:eng
Schlagworte:
aliquat
bistriflimide
guanidinium
hexafluorophosphate
tetrabromocobaltate
tetrachloro-cuprate
tetrachloroferrate
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Zusammenfassung:Crystal structures of five hexaethylguanidinium salts (PF6- 1, FeCl4- 2, CuCl42-*H2O 3, CoBr42-/Br-*H2O 4, bistriflimide 5) were determined. Short interionic contacts were identified. Cyclic voltammetry of 2 revealed an electrochemical window from +1.0 to -1.5 V with a single Fe(III)/Fe(II) redox event at -0.27 V on a gold electrode versus Ag/AgCl.
ISSN:2073-4352
2073-4352
DOI:10.3390/cryst4030404