Towards detailed combustor wall kinetics: An experimental and kinetic modeling study of hydrogen oxidation on Inconel

•New H2-TPR experiments over a wide range of Inconels.•First thermoconsistent multi-site model for H2 oxidation on Inconels.•Non-monotonous effect of surface area on reactivity.•Interactions between surface and gas-phase kinetics unraveled. Gas-phase hydrogen combustion is ubiquitous in industrial processes, and the associated surface kinetics on heat-resistant alloys plays a crucial role in designing efficient low-carbon technologies. We conducted new temperature programmed reduction experiments to determine the reducibility of materials following an oxidation cycle. These experiments were modeled using a thermoconsistent multi-site microkinetic model for H2 heterogeneous oxidation on Inconels, which was validated against literature experiments. This competitive adsorption model considers iron bulk content, hydrogen spillover and subsurface oxygen migration on hydrogen surface oxidation kinetics. New X-ray diffraction experiments confirmed the postulated crystallographic structures in the Inconel samples, suggesting their presence on the surface scale. The phenomenological model was coupled with several state-of-the-art gas-phase oxidation mechanisms to assess gas/surface reactions interaction as a function of material and temperature. The results reveal a complex interaction in which surface removes H radicals from the gas-phase, while the Bradford (H2+OH) reaction converts OH into H2O, promoting water adsorption on Inconel. This interaction was found to give rise to gas-phase thermokinetic oscillations. The model predicts a non-monotonous effect of reactor area-to-volume ratio on reactivity and emphasizes the impact of Inconel composition on product selectivity. Overall, the multi-site model provides new insight into the contrasting reactivities among active sites, bridging the gap between material science and heterogeneous combustion modeling.