Dichlorido{μ-6,6′-dimethoxy-2,2′-[ o -phenylenebis(nitrilomethylidyne)]diphenolato}(dimethyl sulfoxide)lead(II)zinc(II) N , N -dimethylformamide solvate

In the heterodinuclear complex of the title compound, [PbZn(C22H18N2O4)Cl2(C2H6OS)]·C3H7NO, the ZnII atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The PbII atom is coordinat...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-11, Vol.64 (11), p.m1460-m1460
Hauptverfasser: Wang, Hailong, Zhang, Daopeng, Tian, Laijin, Zhang, Li-Fang
Format: Artikel
Sprache:eng
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Zusammenfassung:In the heterodinuclear complex of the title compound, [PbZn(C22H18N2O4)Cl2(C2H6OS)]·C3H7NO, the ZnII atom is coordinated in a distorted square-pyramidal geometry by two N atoms and two O atoms from the diphenolate ligand, and one Cl atom which occupies the apical position. The PbII atom is coordinated in a distorted octahedral geometry by the four O atoms of the diphenolate ligand, one O atom from the dimethyl sulfoxide molecule and one Cl atom. The dimethyl sulfoxide molecule is disordered over two positions, with site occupancies of 0.576 (2) and 0.424 (2).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808034338