Morpholinium styphnate

In the title mol-ecular salt (systematic name: morpholinium 3-hy-droxy-2,4,6-trinitro-phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (-), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendi...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-11, Vol.66 (Pt 11), p.o2698-o2698
Hauptverfasser: Kalaivani, D, Malarvizhi, R
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title mol-ecular salt (systematic name: morpholinium 3-hy-droxy-2,4,6-trinitro-phenolate), C(4)H(10)NO(+)·C(6)H(2)N(3)O(8) (-), two of the nitro groups of the anion are close to parallel with the plane of the benzene ring [dihedral angles = 3.46 (9) and 11.60 (10)°] and one is almost perpendicular [dihedral angle = 82.23 (8)°]. An intra-molecular O-H⋯O hydrogen bond occurs in the anion. The morpholinium cation has a slightly distorted chair conformation. In the crystal, the components are linked by simple N-H⋯O and trifurcated N-H⋯(O,O,O) hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810038304