Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

Crystal structure of triphenyl(vinyl)phosphonium tetraphenylborate

The title ionic salt, C 21 H 20 P + ·C 24 H 20 B − , crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atom...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-10, Vol.70 (10), p.o1143-o1143
Hauptverfasser: Bradfield, Joseph L., Braun, Richard A., White, Frankie, Hendrich, Jeffrey M., Sykora, Richard E., Mirjafari, Arsalan
Format: Artikel
Sprache:eng
Schlagworte:
crystal structure
ionic salt
tetraphenylborate
vinyltriphenylphosphonium
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Zusammenfassung:The title ionic salt, C 21 H 20 P + ·C 24 H 20 B − , crystallized with two independent vinyltriphenylphosphonium cations and two independent tetraphenylborate anions per asymmetric unit. These four independent moieties contain nearly perfect tetrahedral symmetry about their respective central C atoms. In the crystal, there are no π-stacking or other intermolecular interactions present.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536814021357