New insights into the flow dynamics of a deep freshwater aquifer in the semi-arid and saline Cuvelai-Etosha Basin, Northern Namibia: Results of a multi-environmental tracer study

A paleo-megafan system of the Cubango River in the northern parts of the semi-arid Cuvelai-Etosha Basin, shared by Angola and Namibia. It hosts a deep freshwater aquifer, the so-called Kalahari-Ohangwena 2 (KOH-2), with the potential to resolve the imminent regional water supply shortages. Hydrogeochemical and multi-environmental tracer studies incorporating the use of age tracers 14C, 36Cl, 81Kr and 4He to determine the age of groundwater and provide insights into the flow dynamics of the KOH-2. Stable water isotopes and noble gas thermometry show that in a period with higher rainfall and recharge, temperatures were at least 3 – 4 °C lower than today. Several arguments led to the conclusion that younger groundwater, possibly of an age of 35,000 years, is mixed with ancient saline pore water. These include: 1) the correlation of measured 36Cl and 81Kr ratios, as well as 4He concentrations, using a binary mixing model, and 2) the substantial variation in 81Kr ages, ranging from 40,000 to 170,000 years, over relatively short distances—a phenomenon challenging to explain by advective groundwater flow equations. Consequently, the ages derived from 81Kr measurements serve as indicators of the extent of freshening and therefore describe mixing ages rather than absolute travel times. [Display omitted] •Environmental tracer application reveals mixing of fresh and old saline groundwater.•Krypton-81 successfully used to date groundwater with an age of 40000–170000 years.•Correlation of helium4 with krypton- 81 allows age determination of groundwater.•Major recharge event characterised by cooler temperatures occurred before LGM.