Distinct relaxation mechanism at room temperature in metallic glass

How glasses relax at room temperature is still a great challenge for both experimental and simulation studies due to the extremely long relaxation time-scale. Here, by employing a modified molecular dynamics simulation technique, we extend the quantitative measurement of relaxation process of metall...

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Veröffentlicht in:Nature communications 2023-02, Vol.14 (1), p.540-540, Article 540
Hauptverfasser: Sun, Yi-Tao, Zhao, Rui, Ding, Da-Wei, Liu, Yan-Hui, Bai, Hai-Yang, Li, Mao-Zhi, Wang, Wei-Hua
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Sprache:eng
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Zusammenfassung:How glasses relax at room temperature is still a great challenge for both experimental and simulation studies due to the extremely long relaxation time-scale. Here, by employing a modified molecular dynamics simulation technique, we extend the quantitative measurement of relaxation process of metallic glasses to room temperature. Both energy relaxation and dynamics, at low temperatures, follow a stretched exponential decay with a characteristic stretching exponent β  = 3/7, which is distinct from that of supercooled liquid. Such aging dynamics originates from the release of energy, an intrinsic nature of out-of-equilibrium system, and manifests itself as the elimination of defects through localized atomic strains. This finding is also supported by long-time stress-relaxation experiments of various metallic glasses, confirming its validity and universality. Here, we show that the distinct relaxation mechanism can be regarded as a direct indicator of glass transition from a dynamic perspective. The mechanism governing structural relaxation in metallic glasses remains elusive, hampering their stability and engineering applications. Here, the authors reveal a distinct relaxation mechanism with a stretching exponent of 3/7, providing new insight for understanding the nature of glass.
ISSN:2041-1723
2041-1723
DOI:10.1038/s41467-023-36300-x