Chlorido(η 6 - p -cymene)[2-(5-phenyl-4 H -1,2,4-triazol-3-yl-κ N 2 )pyridine-κ N ]ruthenium(II) chloride

In the title compound, [RuCl(C 10 H 14 )(C 13 H 10 N 4 )]Cl, the pyridyltriazole fragment of the bidentate ligand is essentially planar [dihedral angle = 0.8 (1)°], while the phenyl substituent is inclined at 19.4 (1)° to the 1,2,4-triazole ring. In the crystal, the complex cations are packed in she...

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Veröffentlicht in:IUCrData 2018-05, Vol.3 (5), p.x180625, Article x180625
1. Verfasser: Sikalov, Alexander
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [RuCl(C 10 H 14 )(C 13 H 10 N 4 )]Cl, the pyridyltriazole fragment of the bidentate ligand is essentially planar [dihedral angle = 0.8 (1)°], while the phenyl substituent is inclined at 19.4 (1)° to the 1,2,4-triazole ring. In the crystal, the complex cations are packed in sheets with no particularly strong interactions between them. The Cl − anions are bound to the cations by unusually strong N—H...Cl hydrogen bonds.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314618006259