Soft chemical control of the crystal and magnetic structure of a layered mixed valent manganite oxide sulfide

Oxidative deintercalation of copper ions from the sulfide layers of the layered mixed-valent manganite oxide sulfide Sr2MnO2Cu1.5S2 results in control of the copper-vacancy modulated superstructure and the ordered arrangement of magnetic moments carried by the manganese ions. This soft chemistry ena...

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Veröffentlicht in:	APL materials 2015-04, Vol.3 (4), p.041520-041520-6
Hauptverfasser:	Blandy, Jack N., Abakumov, Artem M., Christensen, Kirsten E., Hadermann, Joke, Adamson, Paul, Cassidy, Simon J., Ramos, Silvia, Free, David G., Cohen, Harry, Woodruff, Daniel N., Thompson, Amber L., Clarke, Simon J.
Format:	Artikel
Sprache:	eng
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Zusammenfassung:	Oxidative deintercalation of copper ions from the sulfide layers of the layered mixed-valent manganite oxide sulfide Sr2MnO2Cu1.5S2 results in control of the copper-vacancy modulated superstructure and the ordered arrangement of magnetic moments carried by the manganese ions. This soft chemistry enables control of the structures and properties of these complex materials which complement mixed-valent perovskite and perovskite-related transition metal oxides.
ISSN:	2166-532X 2166-532X
DOI:	10.1063/1.4918973