t-3-Ethyl-r-2,c-7-bis-(4-methoxy-phen-yl)-1,4-diazepan-5-one

The title compound, C(21)H(26)N(2)O(3), crystallizes with two independent mol-ecules in the asymmetric unit. In both independent mol-ecules, the diazepine ring adopts a chair conformation. In the crystal, the independent mol-ecules exist as N-H⋯O hydrogen-bonded R(2) (2)(8) dimers which are linked v...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-10, Vol.65 (Pt 11), p.o2885-o2886
Hauptverfasser: Ravichandran, K, Ramesh, P, Sethuvasan, S, Ponnuswamy, S, Ponnuswamy, M N
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, C(21)H(26)N(2)O(3), crystallizes with two independent mol-ecules in the asymmetric unit. In both independent mol-ecules, the diazepine ring adopts a chair conformation. In the crystal, the independent mol-ecules exist as N-H⋯O hydrogen-bonded R(2) (2)(8) dimers which are linked via N-H⋯O hydrogen bonds, forming tetra-mers. The tetra-mers are linked by C-H⋯O hydrogen bonds. In one of the molecules in the asymmetric unit, the terminal C atom of the ethyl group is disordered over two positions with refined occupancies of 0.742 (4) and 0.258 (4).
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809043311