cis -Diiodido( N , N , N ′, N ′-tetramethylethylenediamine-κ 2 N , N ′)palladium(II)
In the title complex, cis -[PdI 2 (C 6 H 16 N 2 )], the Pd II atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating N , N , N ′, N ′-tetramethylethylenediamine ligand [Pd—N = 2.125 (3) Å] and two I atoms [Pd—I = 2.5833 (4) Å], displaying a di...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-08, Vol.68 (8), p.m1129-m1129 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | In the title complex,
cis
-[PdI
2
(C
6
H
16
N
2
)], the Pd
II
atom lies on a crystallographic twofold rotation axis and is four-coordinated by the two N atoms of a chelating
N
,
N
,
N
′,
N
′-tetramethylethylenediamine ligand [Pd—N = 2.125 (3) Å] and two I atoms [Pd—I = 2.5833 (4) Å], displaying a distorted square-planar geometry (r.m.s. deviation = 0.005 Å), imposed by the small bite of the chelating ligand [N—Pd—N angle = 84.68 (18)°]. |
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| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536812033004 |