2-(1,3-Dioxoisoindolin-2-yl)acetic acid #8211;N #8242;-[(E)-4-methoxybenzylidene]pyridine-4-carbohydrazide (2/1)

In the crystal structure of the title compound, 2C10H7NO4·C14H13N3O2, the two independent acid molecules are connected through strong O—H...N and O—H...O hydrogen bonds to the central molecule of the antitubercular drug N′-[(E)-4-methoxybenzylidene]pyridine-4-c...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-10, Vol.68 (10), p.o2897-o2898
Hauptverfasser: Sladjana B. Novakovi&#263, Goran A. Bogdanovi&#263, Shaaban K. Mohamed, Mustafa R. Albayati, Ayad S. Hameed
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In the crystal structure of the title compound, 2C10H7NO4·C14H13N3O2, the two independent acid molecules are connected through strong O—H...N and O—H...O hydrogen bonds to the central molecule of the antitubercular drug N′-[(E)-4-methoxybenzylidene]pyridine-4-carbohydrazide. Two such trimolecular units related by an inversion centre interact through a pair of N—H...O hydrogen bonds, forming a 3 + 3 molecular aggregate. The dihedral angle between the aromatic rings of the hydrazone molecule is 1.99 (12)°. The crystal packing features weak C—H...O and π–π stacking interactions, with centroid–centroid distances of 3.8460 (19) and 3.8703 (13) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812038032