Construction of Triboelectric Series and Chirality Detection of Amino Acids Using Triboelectric Nanogenerator

Triboelectrification necessitates a frictional interaction between two materials, and their contact electrification is characteristically based on the polarity variance in the triboelectric series. Utilizing this fundamental advantage of the triboelectric phenomenon, different materials can be identified according to their contact electrification capability. Herein, an in‐depth analysis of the amino acids present in the stratum corneum of human skin is performed and these are quantified regarding triboelectric polarization. The principal focus of this study lies in analyzing and identifying the amino acids present in copious amounts in the stratum corneum to explain their positive behavior during the contact electrification process. Thus, an augmented triboelectric series of amino acids with quantified triboelectric charging polarity by scrutinizing the transfer charge, work function, and atomic percentage is presented. Furthermore, the chirality of aspartic acid as it is most susceptible to racemization with clear consequences on the human skin is detected. The study is expected to accelerate research exploiting triboelectrification and provide valuable information on the surface properties and biological activities of these important biomolecules. Triboelectrification relies on friction between two materials, exploiting the polarity variations in the triboelectric series for contact electrification. The study delves into amino acids in human skin's stratum corneum, quantifying their triboelectric properties. It emphasizes high‐abundance amino acids in the skin's outer layer, presenting an extended triboelectric series. Additionally, it identifies homochiral aspartic acid susceptible to the racemization process.