Nitrogen-Doped Porous Carbon Nanosheets Strongly Coupled with Mo2C Nanoparticles for Efficient Electrocatalytic Hydrogen Evolution

Exploring earth-abundant and noble metal-free catalysts for water electrolysis is pivotal in renewable hydrogen production. Herein, a highly active electrocatalyst of nitrogen-doped porous carbon nanosheets coupled with Mo 2 C nanoparticles (Mo 2 C/NPC) was synthesized by a novel method with high BE...

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Veröffentlicht in:Nanoscale research letters 2019-10, Vol.14 (1), p.1-8, Article 329
Hauptverfasser: Lei, Ying, Yang, Yong, Liu, Yudong, Zhu, Yaxing, Jia, Mengmeng, Zhang, Yang, Zhang, Ke, Yu, Aifang, Liu, Juan, Zhai, Junyi
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Sprache:eng
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Zusammenfassung:Exploring earth-abundant and noble metal-free catalysts for water electrolysis is pivotal in renewable hydrogen production. Herein, a highly active electrocatalyst of nitrogen-doped porous carbon nanosheets coupled with Mo 2 C nanoparticles (Mo 2 C/NPC) was synthesized by a novel method with high BET surface area of 1380 m 2  g −1 using KOH to activate carbon composite materials. The KOH plays a key role in etching out MoS 2 to produce Mo precursor; simultaneously, it corrodes carbon to form porous structure and produce reducing gas such as H 2 and CO. The resulting Mo 2 C/NPC hybrid demonstrated superior HER activity in acid solution, with the overpotential of 166 mV at current density of 10 mA cm −2 , onset overpotential of 93 mV, Tafel slope of 68 mV dec −1 , and remarkable long-term cycling stability. The present strategy may provide a promising strategy to fabricate other metal carbide/carbon hybrids for energy conversion and storage.
ISSN:1931-7573
1556-276X
DOI:10.1186/s11671-019-3147-z