trans -Bis(acetato-κ O )bis(2-aminoethanol-κ 2 N , O )nickel(II)
In the title compound, [Ni(CH 3 CO 2 ) 2 (C 2 H 7 NO) 2 ], the Ni II cation, located on an inversion center, is N , O -chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intra...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-05, Vol.68 (5), p.m567-m568 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | In the title compound, [Ni(CH
3
CO
2
)
2
(C
2
H
7
NO)
2
], the Ni
II
cation, located on an inversion center, is
N
,
O
-chelated by two 2-aminoethanol molecules and further coordinated by two monodendate acetate anions in a slightly distorted octahedral geometry. The latter is stabilized by intramolecular O—H⋯O hydrogen bonds involving the non-coordinated O atom of the acetate and the H atom of the hydroxy group of the 2-aminoethanol ligand. In the crystal, N—H⋯O hydrogen bonds link the molecules into a three-dimensional supramolecular framework that involves (
a
) the coordinated acetate O atom and one of the H atoms of the amino group and (
b
) the non-coordinated acetate O atom and the other H atom of the amino group. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812014237 |