A dodecamethoxy[6]cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure

A dodecamethoxy[6]cycloparaphenylene consisting entirely of hydroquinone ethers: unveiling in-plane aromaticity through a rotaxane structure

[ n ]Cycloparaphenylenes ([ n ]CPPs, where n is the number of phenylene groups), consisting of 1,4-linked phenylene unit, have attracted much attention due to their cyclic π-conjugated structures and physical properties. However, functionalizing of the benzene rings of smaller [ n ]CPPs ( n  

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Veröffentlicht in:Nature communications 2023-12, Vol.14 (1), p.8091-8091, Article 8091
Hauptverfasser: Narita, Naoki, Kurita, Yusuke, Osakada, Kohtaro, Ide, Tomohito, Kawai, Hidetoshi, Tsuchido, Yoshitaka
Format: Artikel
Sprache:eng
Schlagworte:
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639/301/923/3931
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639/638/541/964
Aromaticity
Benzene
Conformation
Ethers
Humanities and Social Sciences
Hydrocarbons
Hydroquinone
Molecular conformation
Molecular structure
multidisciplinary
Oxidation
Physical properties
Rotaxanes
Science
Science (multidisciplinary)
Steric hindrance
Synthesis
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Zusammenfassung:[ n ]Cycloparaphenylenes ([ n ]CPPs, where n is the number of phenylene groups), consisting of 1,4-linked phenylene unit, have attracted much attention due to their cyclic π-conjugated structures and physical properties. However, functionalizing of the benzene rings of smaller [ n ]CPPs ( n  
ISSN:2041-1723
2041-1723
DOI:10.1038/s41467-023-43907-7