2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone

2-Azido-1-(3,6-dichloro-9H-fluoren-1-yl)ethanone

In the title compound, C(15)H(9)Cl(2)N(3)O, an intra-molecular C-H⋯O inter-action generates an S(7) ring motif. The cyclo-penta-1,3-diene ring forms dihedral angles of 1.93 (6) and 2.78 (6)° with its attached benzene rings. In the crystal, mol-ecules are linked by C-H⋯N and C-H⋯O hydrogen bonds, the...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-10, Vol.67 (Pt 10), p.o2656-o2657
Hauptverfasser: Fun, Hoong-Kun, Chia, Tze Shyang, Kayarmar, Reshma, Dinesha, Nagaraja, G K
Format: Artikel
Sprache:eng
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Organic Papers
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Zusammenfassung:In the title compound, C(15)H(9)Cl(2)N(3)O, an intra-molecular C-H⋯O inter-action generates an S(7) ring motif. The cyclo-penta-1,3-diene ring forms dihedral angles of 1.93 (6) and 2.78 (6)° with its attached benzene rings. In the crystal, mol-ecules are linked by C-H⋯N and C-H⋯O hydrogen bonds, thereby forming layers lying parallel to the ac plane. The crystal also features a π-π inter-action with a centroid-centroid distance of 3.5612 (6) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811036762