A novel l-amino acid ionic liquid for quick and highly efficient synthesis of oxime derivatives – An environmental benign approach

A mild, efficient, and eco-friendly procedure for the conversion of aliphatic, alicyclic and aromatic carbonyl compounds into the corresponding oximes, was catalyzed by a novel imidazolium based ionic liquid coupled with amino acid (asparagine) (l-AAIL, l-Amino acid functionalized ionic liquid) cata...

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Veröffentlicht in:Arabian journal of chemistry 2016-11, Vol.9 (S2), p.S1036-S1039
Hauptverfasser: Karthikeyan, Parasuraman, Aswar, Sachin Arunrao, Muskawar, Prashant Narayan, Sythana, Suresh Kumar, Bhagat, Pundlik Rambhau, Kumar, Sellappan Senthil, Satvat, Pranveer S.
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Sprache:eng
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Zusammenfassung:A mild, efficient, and eco-friendly procedure for the conversion of aliphatic, alicyclic and aromatic carbonyl compounds into the corresponding oximes, was catalyzed by a novel imidazolium based ionic liquid coupled with amino acid (asparagine) (l-AAIL, l-Amino acid functionalized ionic liquid) catalytic system. The quantitative conversion of aryl and alkyl carbonyl compounds into the corresponding oximes was achieved by simply grinding at ambient temperature using 0.05mmol of catalyst in 50s. In addition, this L-AAIL catalyst exhibited good reusability for five consecutive trials without significant loss of its catalytic activity.
ISSN:1878-5352
1878-5379
DOI:10.1016/j.arabjc.2011.11.007