Wavepacket Splitting in the First 100 fs Determines the Products from the Bond Cleavage of Diphenylmethylchloride

Wavepacket Splitting in the First 100 fs Determines the Products from the Bond Cleavage of Diphenylmethylchloride

An elementary chemical reaction proceeds through two distinct conical intersections. Benzhydryl radicals are formed with a delay of 80 fs, cations after 125 fs. The optical signal increases more slowly due to planarization and solvation.

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Veröffentlicht in:EPJ Web of conferences 2013-01, Vol.41, p.5042-np
Hauptverfasser: Sailer, C.F., Krebs, N., Fingerhut, B.P., de Vivie-Riedle, R., Riedle, E.
Format: Artikel
Sprache:eng
Schlagworte:
Bonding
Chemical reactions
Cleavage
Delay
Planarization
Radicals
Solvation
Splitting
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Beschreibung
Zusammenfassung:An elementary chemical reaction proceeds through two distinct conical intersections. Benzhydryl radicals are formed with a delay of 80 fs, cations after 125 fs. The optical signal increases more slowly due to planarization and solvation.
ISSN:2100-014X
2100-014X
DOI:10.1051/epjconf/20134105042