2-Methylsulfanylbenzo[f]isoquinoline

2-Methylsulfanylbenzo[f]isoquinoline

S-Methylation of a 4-(naphth-2-yl)-β-thiolactam gives an intermediate 4-(naphth-2-yl) substituted 1-azetine which undergoes a [2+2] ring-opening followed by electrocyclic ring closure of the resulting 2-azadiene to give a benzo[f]isoquinoline.

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Bibliographische Detailangaben
Veröffentlicht in:MolBank 2015-05, Vol.2015 (2), p.M860
Hauptverfasser: Jamshaid, Faisal, Khan, Musharraf, Hemming, Karl
Format: Artikel
Sprache:eng
Schlagworte:
1-azetine
benzoisoquinoline
naphthalene
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Beschreibung
Zusammenfassung:S-Methylation of a 4-(naphth-2-yl)-β-thiolactam gives an intermediate 4-(naphth-2-yl) substituted 1-azetine which undergoes a [2+2] ring-opening followed by electrocyclic ring closure of the resulting 2-azadiene to give a benzo[f]isoquinoline.
ISSN:1422-8599
1422-8599
DOI:10.3390/M860