Bis{1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olato}copper(II)

The Cu(II) atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra-coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol-ecules are linked via...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-07, Vol.69 (Pt 7), p.m405-m405
Hauptverfasser: Benaouida, Mohamed Amine, Benosmane, Ali, Bouguerria, Hassiba, Bouaoud, Salah Eddine, Merazig, Hocine
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Sprache:eng
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Zusammenfassung:The Cu(II) atom in the title compound, [Cu(C16H10ClN2O)2], is located on an inversion center and is tetra-coordinated by two N and two O atoms from two bidentate 1-[(E)-(2-chloro-phen-yl)diazen-yl]naphthalen-2-olate ligands, forming a square-planar complex. In the crystal, mol-ecules are linked via weak C-H⋯O and C-H⋯Cl hydrogen bonds, forming chains propagating along [010]. There are also π-π inter-actions present involving adjacent naphthalene rings [centroid-centroid distance = 3.661 (13) Å].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813016681