Numerical simulation on the generation characteristics of nitrogen-containing pollutants during co-gasification process of biomass and polyethylene

The co-gasification of biomass and polyethylene in an updraft gasifier can effectively increase the calorific value of the syngas and the H2 yield. However, the generation and emission characteristics of nitrogen-containing pollutants during the co-gasification process have not yet been fully understood. Therefore, this study constructed a two-dimensional mathematical model of gas-solid flow coupling with chemical reaction in updraft gasifier based on the particle dynamics theory and Euler-Euler method, and investigated the effects of air equivalence ratio (ER), the blending ratio of biomass and polyethylene, and steam-to-fuel ratio (S/F) on the generation characteristics of nitrogen-containing pollutants. The results showed that NH3 and HCN mainly came from the pyrolysis of biomass volatiles during the co-gasification process of biomass and polyethylene, and therefore they were mainly distributed in the pyrolysis zone and dry zone of the updraft gasifier. The generation of NO mainly came from the combustion