Preparação de um Sinton Funcionalizado a Partir da Carvona Visando a Síntese de alfa-metileno-gama-butirolactonas Monoterpênicas

Preparação de um Sinton Funcionalizado a Partir da Carvona Visando a Síntese de alfa-metileno-gama-butirolactonas Monoterpênicas

(R)-(-)-Carvone (6) has been transformed into oxygenated derivative 13, which is expected to be a useful synthon or chiral template in the synthesis of natural a-methylene-g-butyrolactones. This synthesis of compound 13 involves classics reactions of oxygenation in saturated carbon with full control...

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Veröffentlicht in:Orbital : The Electronic Journal of Chemistry 2015-12, Vol.7 (4), p.395-400
Hauptverfasser: Dos Santos, Reginaldo Bezerra, Cesar, Roberta Cecília Vettoraci, Lacerda Jr, Valdemar, Greco, Sandro Jose, Neto, Alvaro Cunha
Format: Artikel
Sprache:eng
Schlagworte:
(r)-(-)-carvone
alfa-methylene-gama-butyrolactones
monoterpene
stereoselective synthesis
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Zusammenfassung:(R)-(-)-Carvone (6) has been transformed into oxygenated derivative 13, which is expected to be a useful synthon or chiral template in the synthesis of natural a-methylene-g-butyrolactones. This synthesis of compound 13 involves classics reactions of oxygenation in saturated carbon with full control of regioselectivity and stereoselectivity.   DOI: http://dx.doi.org/10.17807/orbital.v7i4.728
ISSN:1984-6428
1984-6428
DOI:10.17807/orbital.v7i4.728