2-Hydroxy-16-[( E )-4-hydroxy-3-methoxybenzylidene]-13-(4-hydroxy-3-methoxyphenyl)-11-methyl-1,11-diazapentacyclo[12.3.1.0 2,10 .0 3,8 .0 10,14 ]octadeca-3(8),4,6-triene-9,15-dione

In the title compound, C32H30N2O7, the piperidone ring adopts a chair conformation and the five-membered ring of the dihydroindenone ring system adopts an envelope conformation. Intramolecular O—H...N and C—H...O hydrogen bonds occur. The dihedral angle between the two hydroxy-su...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-06, Vol.66 (6), p.o1370-o1371
Hauptverfasser: Kumar, Raju Suresh, Osman, Hasnah, Ali, Mohamed Ashraf, Hemamalini, Madhukar, Fun, Hoong-Kun
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, C32H30N2O7, the piperidone ring adopts a chair conformation and the five-membered ring of the dihydroindenone ring system adopts an envelope conformation. Intramolecular O—H...N and C—H...O hydrogen bonds occur. The dihedral angle between the two hydroxy-subsituted methoxyphenyl rings is 71.12 (5)°. In the crystal structure, molecules are connected by intermolecular O—H...O hydrogen bonds, forming layers parallel to (001). These layers are further connected by C—H...O hydrogen bonds, forming a three-dimensional network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810017216