(Salen)Mn(III) Catalyzed Asymmetric Epoxidation Reactions by Hydrogen Peroxide in Water: A Green Protocol

Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H₂O employing H₂O₂ as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values...

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Veröffentlicht in:	International journal of molecular sciences 2016-07, Vol.17 (7), p.1112-1112
Hauptverfasser:	Ballistreri, Francesco Paolo, Gangemi, Chiara M A, Pappalardo, Andrea, Tomaselli, Gaetano A, Toscano, Rosa Maria, Trusso Sfrazzetto, Giuseppe
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Asymmetry Catalysis Chemical reactions Communication enantioselectivity epoxidation Ethylenediamines - chemistry Green Chemistry Technology Hydrogen peroxide Hydrogen Peroxide - chemistry jacobsen catalyst Organometallic Compounds - chemistry Stereoisomerism Surface-Active Agents - chemistry Water Water - chemistry
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Zusammenfassung:	Enantioselective epoxidation reactions of some chosen reactive alkenes by a chiral Mn(III) salen catalyst were performed in H₂O employing H₂O₂ as oxidant and diethyltetradecylamine N-oxide (AOE-14) as surfactant. This procedure represents an environmentally benign protocol which leads to e.e. values ranging from good to excellent (up to 95%).
ISSN:	1422-0067 1661-6596 1422-0067
DOI:	10.3390/ijms17071112