Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N -arylaminocyclopropane with alkyne derivatives

Dirhodium(II)-catalyzed [3 + 2] cycloaddition of N -arylaminocyclopropane with alkyne derivatives

Dirhodium(II) complex-catalyzed [3 + 2] reactions between -arylaminocyclopropanes and alkyne derivatives are described. The cycloaddition products proved to be versatile synthetic intermediates. -Cyclic β-amino acids and derivatives thereof can be conveniently synthesized using this cycloaddition pr...

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Veröffentlicht in:Beilstein journal of organic chemistry 2019-02, Vol.15 (1), p.542-550
Hauptverfasser: Liu, Wentong, Kuang, Yi, Wang, Zhifan, Zhu, Jin, Wang, Yuanhua
Format: Artikel
Sprache:eng
Schlagworte:
3 + 2
alkyne
Amino acids
Chemistry
cycloaddition
cyclopropanes
dirhodium catalysis
Full Research Paper
Intermediates
N-arylaminocyclopropanes
Nitrogen
Solvents
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Zusammenfassung:Dirhodium(II) complex-catalyzed [3 + 2] reactions between -arylaminocyclopropanes and alkyne derivatives are described. The cycloaddition products proved to be versatile synthetic intermediates. -Cyclic β-amino acids and derivatives thereof can be conveniently synthesized using this cycloaddition protocol.
ISSN:1860-5397
2195-951X
1860-5397
DOI:10.3762/bjoc.15.48