Crystal structure of 1-[2-(4-nitro-phen-yl)-4,5-diphenyl-1 H -imidazol-1-yl]propan-2-ol

The title compound, C H N O , crystallizes with two unique but closely r.m.s. overlay fit = 0.215 Å) comparable mol-ecules (1 and 2) in the asymmetric unit of the triclinic unit cell. In molecule 1, the dihedral angles between the central imidazlole ring and the benzene-ring substituents are 42.51 (...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-09, Vol.73 (Pt 9), p.1398-1401
Hauptverfasser: Simpson, Jim, Mohamed, Shaaban K, Marzouk, Adel A, Abdelhamid, Antar A, Albayati, Mustafa R
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Sprache:eng
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Zusammenfassung:The title compound, C H N O , crystallizes with two unique but closely r.m.s. overlay fit = 0.215 Å) comparable mol-ecules (1 and 2) in the asymmetric unit of the triclinic unit cell. In molecule 1, the dihedral angles between the central imidazlole ring and the benzene-ring substituents are 42.51 (9), 45.41 (9) and 56.92 (8)°, respectively. Comparable data for molecule 2 are 39.36 (10), 34.45 (11) and 60.34 (8)°, respectively. The rings at the 2-positions carry -nitro substituents that subtend dihedral angles of 12.9 (4)° in mol-ecule 1 and 11.7 (4)° in mol-ecule 2 to their respective benzene ring planes. The imidazole rings also have propan-2-ol substituents on the 1-N atoms, which adopt extended conformations for the N-C-C-C chains. In the crystal, classical O-H⋯N hydrogen bonds combine with C-H⋯O, C-H⋯N and C-H⋯π(ring) hydrogen bonds and stack the molecules along the -axis direction.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989017011057