Bis[2-(1 H -benzotriazol-1-yl)-1 H -benzimidazol-1-ido]diethanolcadmium

In the title complex, [Cd(C13H8N5)2(C2H5OH)2], the CdII cation is located on an inversion center and coordinated by two deprotonated 2-(1H-benzotriazol-1-yl)-1H-benzimidazol-1-ide (L) ligands and two ethanol molecules in a distorted N4O2 octahedral geometry. In the L ligand, the dihedral angle betwe...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-03, Vol.69 (3), p.m134-m134
Hauptverfasser: Cao, Ping, Liu, Jia-Cheng, Hu, Dong-Cheng
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title complex, [Cd(C13H8N5)2(C2H5OH)2], the CdII cation is located on an inversion center and coordinated by two deprotonated 2-(1H-benzotriazol-1-yl)-1H-benzimidazol-1-ide (L) ligands and two ethanol molecules in a distorted N4O2 octahedral geometry. In the L ligand, the dihedral angle between benzoimidazole and benzotriazole ring systems is 10.8 (3)°. In the crystal, the complex molecules are connected by O-H...N hydrogen bonds; intermolecular π-π stacking is also observed [centroid-centroid distances of 3.668 (5) Å between triazole and benzene rings and 3.780 (5) Å between imidazole rings].
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813001827