Bis(acetonitrile-κN)dichlorido(η-cyclo-octa-1,5-diene)ruthenium(II) acetonitrile monosolvate
In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphe...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-08, Vol.67 (Pt 8), p.m1096-m1096 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | In the title Ru(II) complex, [RuCl(2)(C(8)H(12))(C(2)H(3)N)(2)]·CH(3)CN, the metal ion is coordinated to the centers of each of the double bonds of the cyclo-octa-diene ligand, to two chloride ions (in cis positions) and to two N-atom donors (from MeCN mol-ecules) that complete the coordination sphere for the neutral complex. The coordination about the Ru(II) atom can thus be considered to be octa-hedral with a slightly trigonal distortion. There is also one acetonitrile solvent mol-ecule per mol-ecule which is outside the coordination sphere of the ruthenium atom. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536811027723 |