The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives

The preparation of several 1,2,3,4,5-functionalized cyclopentane derivatives

With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target...

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Veröffentlicht in:Beilstein journal of organic chemistry 2013-08, Vol.9 (1), p.1705-1712
Hauptverfasser: Kelch, André S, Jones, Peter G, Dix, Ina, Hopf, Henning
Format: Artikel
Sprache:eng
Schlagworte:
bromination
Chemistry
cyclopentanes
esterification
Full Research Paper
permethylcyclopentadiene
polyfunctional compounds
radialenes
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Zusammenfassung:With the goal of eventually synthesizing [5]radialene (3), the still missing member of the parent radialene hydrocarbons, we have prepared the pentaacetates 21 and 31, the pentabromide 29 and the hexabromide 32. In principle these should be convertible by elimination reactions to the desired target molecule.
ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.9.195