An electrochemical sensing of phenolic derivative 4-Cyanophenol in environmental water using a facile-constructed Aurivillius-structured Bi2MoO6

Harmful chemicals are always found in the environment and it is necessary to construct a viable sensor to detect those chemicals. In order to construct an electrochemical sensing platform, designing an electrode using bismuth mixed oxides are more important and which grabbed more attention due to it...

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Veröffentlicht in:Ecotoxicology and environmental safety 2021-01, Vol.208, p.111701, Article 111701
Hauptverfasser: Jesila, J. Antolin, Umesh, N.M., Wang, Sea-Fue, Mani, G., Alothman, Asma A., Alshgari, Razan A.
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Sprache:eng
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Zusammenfassung:Harmful chemicals are always found in the environment and it is necessary to construct a viable sensor to detect those chemicals. In order to construct an electrochemical sensing platform, designing an electrode using bismuth mixed oxides are more important and which grabbed more attention due to its high electrocatalytic ability and conductivity. In this literature, we report a facile synthesis of thorn apple like structured pure bismuth molybdate (Bi2MoO6) using a simple hydrothermal assisted one-step calcination method and we report a facile method to sense 4-cyanophenol by electrochemical technique. Bi2MoO6 modified (Glassy Carbon electrode) GCE possess two linear ranges 0.1–39.1 µM and 46.6–110.1 µM with excellent detection limit 0.008297 µM and 0.01097 µM. Also, this novel sensor is steady with good stability, repeatability, and reproducibility. Successfully, the environmental water sample is analyzed as a real sample with a feasible and quantification results which were compared with HPLC analysis. [Display omitted] •Pure Bi2MoO6 was prepared using a simple hydrothermal assisted calcination process.•An electrochemical technique was used to detect 4-cyanophenol.•DPV method was employed to find virtuous LOD and wide linear range.•Environmental water was successfully analyzed as a real sample.
ISSN:0147-6513
1090-2414
DOI:10.1016/j.ecoenv.2020.111701