trans -Dichloridotetrapyrazineruthenium(II) dichloromethane disolvate

In the title compound, [RuCl2(C4H4N2)4]·2CH2Cl2, the RuII atom occupies a position of 222 symmetry and the C atom of the solvent molecule occupies a site with twofold symmetry. The RuII atom has a slightly distorted octahedral geometry. The pyrazine rings are propeller-like and rotated 45.1...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-09, Vol.68 (9), p.m1193-m1193
Hauptverfasser: Nesterov, Vladimir N., Khan, Wajiha, Rangel, Alexandra E., Smucker, Bradley W.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [RuCl2(C4H4N2)4]·2CH2Cl2, the RuII atom occupies a position of 222 symmetry and the C atom of the solvent molecule occupies a site with twofold symmetry. The RuII atom has a slightly distorted octahedral geometry. The pyrazine rings are propeller-like and rotated 45.1 (1)° from the RuN4 plane. In the crystal, the complex and solvent molecules are bridged by weak C—H...N hydrogen bonds along the c axis. Weak intermolecular C—H...Cl contacts link the complexes in the ab plane, forming a network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812035817