The Acid Catalyzed Reaction of α-Pinene Over Y-Zeolite
The hydration of α-pinene has been studied in the presence of Y-zeolite (Si/Al = 2.89) as a solid acid catalyst. The reaction was performed in batch reactor in isopropyl alcohol at various temperature and reaction time with magnetic stirrer. The acid catalyst hydration reaction of a-pinene yields a...
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Veröffentlicht in: | Indonesian journal of chemistry 2013-05, Vol.13 (1), p.59-65 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The hydration of α-pinene has been studied in the presence of Y-zeolite (Si/Al = 2.89) as a solid acid catalyst. The reaction was performed in batch reactor in isopropyl alcohol at various temperature and reaction time with magnetic stirrer. The acid catalyst hydration reaction of a-pinene yields a complex mixture of monoterpenes, alcohols and hydrocarbons. The selectivity of α-terpineol (the monocyclic alcohol) as main product was 59.20% with a conversion of 83.83% and the non alcoholic as the isomerization co-product as 30% after 60 min at 65 °C. The conversion and selectivity to α-terpineol increase significantly with in increase in temperature and reaction times. |
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ISSN: | 1411-9420 2460-1578 |
DOI: | 10.22146/ijc.21327 |