(4-Amino-pyridine-κ N 1 )(2,2'-bi-pyridine-κ 2 N , N ')(2,2':6',2''-terpyridine-κ 3 N , N ', N '')ruthenium(II) bis-(hexa-fluorido-phosphate) unknown solvate
The title compound, [Ru(C H N )(C H N )(C H N )](PF ) solvent, crystallizes in the triclinic space group with one dicationic Ru complex, two PF anions, and undefined solvent in the asymmetric unit. The cation and anions are linked N-H⋯F hydrogen bonding. One PF anion is disordered over two positions...
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Veröffentlicht in: | IUCrData 2021-03, Vol.6 (Pt 3), p.0 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The title compound, [Ru(C
H
N
)(C
H
N
)(C
H
N
)](PF
)
solvent, crystallizes in the triclinic space group
with one dicationic Ru complex, two PF
anions, and undefined solvent in the asymmetric unit. The cation and anions are linked
N-H⋯F hydrogen bonding. One PF
anion is disordered over two positions, with occupancies 0.634 (8) and 0.366 (8). The solvent, which is located in channels in the crystal, is highly disordered. Reflection contributions from the solvent were added to the calculated structure factors using the
routine [Spek (2015)
C
, 9-18] of the program
, which determined there to be 59 electrons in 264 Å
treated this way per unit cell. Because the exact identity and amount of solvent were unknown, no solvent was included in the atom list or mol-ecular formula. |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S241431462100287X |